The material media study is related to the theoretical attention on the problem of materiality. The material problems of media are beginning to be pushed to the forefront of theoretical thinking in the posthuman era. Under such circumstances, Marxism becomes the important theoretical resources and perspective examining and reflecting on the current situation. Marxs concerns and explorations for technology mainly focus on the relationship between people and things. He probes into the problems of separation of people and things through exploration of goods and capital, alienation and materialization, productivity and other aspects, thus opening the way by which he makes an inquiry into materiality. Follow this footprint, Benjamin is the first one who interprets technology as media, and explores the impacts of things on people, that is new media and new technology to the masses and culture in a positive and affirmative tendency by way of discussing the aura and mediation. The opposite relation between people and things is constantly highlighted and heated up, ranging from the Critical Theory School that focuses on the material content of media repressing and paralyzing the perceptual system of people, to Guy Debord and Jean Baudrillard who fiercely respond to mediation. The study on classical culture of Birmingham School excavates the resistance functions of media culture, which inspired the later study on the problem of media materiality concerning mediation of thing and the thingified media.